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Materials innovation has always been vital to the semiconductor industry. In the past, it was high-κ gate dielectrics. Today, Cobalt is seen as a replacement for Tungsten in middle-of-line (MOL) contacts.What materials innovation will the future bring?A likely answer is Graphene, the wonder material discovered in 2004.Graphene is one atomic layer of carbon, the thinnest and strongest material that has ever existed. It is 200 times stronger than steel and the lightest material known to man (1 square meter weighing around 0.77 mg). It is an excellent electrical and thermal conductor at room temperature with an electron mobility of ~ 200,000cm2.V-1.s-1. At one atomic layer, graphene is flexible and transparent. Other notable properties of Graphene are its uniform absorption of light across the visible and near infrared spectrum and its applicability towards spintronics-based devices.Graphene and Moore’s LawMoore’s Law scaling can be broken down into 4 key areas: Lithography FET Advanced Packaging (2.5D and 3D IC) Interconnect Material Solutions for upcoming nodes are starting to emerge in the first two areas (EUV and Nanowire- or Nanosheet-based FET respectively). Graphene play an important role in the latter two areas. For advanced packaging, Graphene can be used as a heat spreader (to lower overall thermal resistance), or as an EM shield (to lower crosstalk) as part of a 3D IC package.Active Graphene device layers can potentially be stacked on top of each other using a low-temperature transfer process ( 400°C) to allow for a dense heterogeneous “memory near compute” configuration. This is an area DARPA is actively researching as part of its new $1.5 billion Electronics Resurgence Initiative.Regarding interconnects, Copper interconnects are running out of steam and becoming a major IC bottleneck (projected 40% total delay for 7 nm node). Graphene’s high electron mobility and thermal conductivity make it an attractive interconnect material for MOL and back-end-of-line (BEOL), especially at line widths 30 nm.Graphene Device ApplicationsGraphene-based semiconductor applications are already starting to hit the market. A fully integrated optical transceiver (with a Graphene modulator and photodetector) operating at 25 Gb/s/channel was on display at the recent Mobile World Congress in Barcelona. San Diego-based Nanomedical Diagnostics is selling a medical device that uses a Graphene biosensor. Europe-based Emberion is building Graphene optoelectronic sensors that might find a home in LIDAR applications, where there is currently a focus on improving sensing in low-light conditions.What will the overall Graphene roadmap in the semiconductor industry look like? The history of ion implantation serves as a good example of how a fundamental scientific discovery moves from the lab to the foundry floor.The dominant view in the semiconductor industry at the time was that ion implantation would not work in practice (vs. thermal diffusion) and that, if it did, it would only marginally improve the manufacturing yields of existing products. There was nothing obvious about the transfer of ion bombardment techniques from nuclear physics research to semiconductor production.Varian (led by British physicist Peter Rose) built a new, advanced ion implant tool that Mostek (DRAM manufacturer based in Texas) was able to use to create MOS ICs with clear competitive advantages. The successful collaboration between Varian and Mostek was the turning point in the development of ion implantation as a major semiconductor manufacturing process. Over the next few years, semiconductor firms used ion implantation in a growing number of process steps and, by the late 1970s, it became one of the main processes used in semiconductor manufacturing.Likewise, the Graphene world needs to work closely with the semiconductor industry to develop the tools and techniques required to solve fundamental issues around Graphene growth (good uniformity over large area, low defect density) and Graphene transfer (high throughput, CMOS compatible). It is only then will we fully realize a future that includes 2D materials.The first step in this process is cross-industry education and initiating the dialogue between semiconductor industry and graphene companies. The National Graphene Association will be hosting the largest gathering of graphene companies and commercial stakeholders at the Global Graphene Expo Conference, October 15-17, 2018, in Austin, Texas.Learn more about graphene at the upcoming Global Graphene Expo Conference with dedicated panels of experts and investors, and roundtable discussions on how Graphene will impact the semiconductor industry. The event promo code is SEMINGA. About the AuthorAnand Chamarthy is the CEO and Co-Founder of Lab 91, an Austin-based startup that is working towards Graphene/CMOS integration at the foundry level. Anand can be reached at [email protected]. About the National Graphene AssociationThe National Graphene Association is the main organization and body in the U.S. promoting and advocating for commercialization of graphene and addressing critical issues such as standards and policy development.
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With chipmakers looking toward 5nm manufacturing, it’s clear that traditional scaling is not dead but continuing in combination with other technologies. The industry sees scaling enabled by 3D architectures such as die stacking and the stacking of very small geometry wafers. Interconnect scaling also comes into play. This year’s Scaling Technologies TechXPOT at SEMICON West (Scaling Every Which Way! – Thursday, July 12, 2:00PM-4:00PM) will provide an update on the evolution of scaling and describe how the various players (foundry, IDM, fabless, and application developers) are jockeying for innovation leadership. As a prelude to the event, SEMI asked speakers to provide insights on important scaling trends. For a full list of speakers and program agenda, visit http://www.semiconwest.org/programs-catalog/scaling-every-which-way.Challenges for gate-all-around (GAA) and FinFET devicesDiederik Verkest, imec Distinguished Member of Technical Staff, Semiconductor Technology and Systems“During the processing of GAA devices, there are ‘non-line-of-sight’ hidden features that are difficult to control and characterize and may also lead to new defect mechanisms that would impact yield, and possibly product reliability.”Common performance boosters for gate-all-around (GAA) FETs and FinFETs include lower access resistance, lower parasitic capacitance, and stress. “However, one specific performance booster that only applies to GAA is the reduction of the spacing between the vertical wires or sheets,” says Diederik Verkest, imec distinguished member of technical staff, Semiconductor Technology and Systems. “This reduces parasitic capacitance without affecting drive current and hence benefits both performance and power.” He further notes that imec demonstrated the first stacked gate-all-around (GAA) devices in scaled nodes. “In fact, we are the only ones that published working circuits – ring oscillators in a scaled node using industry-standard processes – in our case replacement metal gate (RMG), and embedded in situ doped source/drain (S/D) epitaxy.”“There are two elements of the stacked GAA architecture that need to be addressed,” says Verkest. “The first is that this architecture uses epitaxially-grown layers of Si and SiGe to define the device channel. The use of grown materials for the channel and the lattice mismatch between the two materials represent a departure from the traditional fabrication of CMOS devices, so the industry needs to develop and gain confidence in novel metrology that allows for good control of the layers and also proves their low defectivity.” The second aspect is the three-dimensional nature of the GAA devices. “During the processing of these devices, we have ‘non-line-of-sight’ hidden features that are difficult to control and characterize and may also lead to new defect mechanisms that would impact yield, and possibly product reliability.”Huiming Bu, Director, Advanced Logic/Memory Research - Integration and Device, IBM Research, Semiconductor Group"A new device architecture beyond FinFET is required to provide a full technology node scaling benefit (i.e., density, power and performance) at 5nm and 3nm.”Huiming Bu, director, Advanced Logic/Memory Research - Integration and Device, IBM Research, Semiconductor Group, says that naming of technology nodes has been used extensively for marketing strategies in “foundry land,” but the designations have lost much of their meaning as technology scaling differentiators. “That said, when it comes to technology innovation and value proposition, IBM, in conjunction with Samsung and GLOBALFOUNDRIES, has developed the GAA NanoSheet transistor for 5nm to provide a full technology node scaling benefit in density, power and performance,” says Bu (Figure 1). The key parameters for intrinsic device optimization when scaling to the 3nm node, explains Bu, are the NanoSheet width for better electrostatic characteristics, and the number of sheets for increased current density. Also necessary are strain engineering for carrier transport enhancement, and interconnect innovations for parasitic RC reduction. “Beyond that, the industry needs to look into something different, something more disruptive.”Figure 1. TEM cross section of stacked NanoSheet transistors. SOURCE: IBM Research Materials challengesMaterials challenges are also a concern as the industry moves to 5nm and below. “We see increasing complexity in the material systems that are being used,” explains Verkest. One example he cites in scaled FinFET or GAA technologies is the use of two to three layers of different materials – typically metals such as TiN – to which small amounts of other elements are added to set device characteristics such as the threshold voltage. “At the same time, the requirements for the thickness of these materials, driven by gate dimensions for example, or the distance between the wires, are increasingly challenging.” Other examples of materials challenges are the use of two to three different types of insulators in the middle-of-the-line, each with different etch contrasts. “We use novel materials such as carbon containing oxides or oxynitrides that have lower dielectric constants in order to boost the performance of circuits,” he says, noting that the materials list “is quite long.”Several critical dimensions in transistors at advanced technology nodes have already reached a few monolayers of atoms, fueling expectations for innovation at the material level for transistor scaling, Bu notes. “The other argument is that there is a growing gap between computing demand and the slowdown of technology advancement driven by conventional scaling,” says Bu. One trend that addresses this gap is integrating more computing functions that make the technology solution more modular, which naturally leads to the incorporation of more materials for more applications. Bu cautions, however, that introducing new materials in semiconductor technology has never been easy. “It takes many years of R D to reach this implementation point, if it ever happens. So, do we need new materials when the industry moves to 5nm and 3nm? Yes, though I expect new material implementation to be a lot faster in interconnect and packaging at these nodes rather than intrinsic to the transistor.” Challenges in developing atomic-level processesThere will be challenges in developing atomic-level processes used in scaling, such as atomic layer depositions (ALD) and atomic layer etches, notes Verkest. “These classes of processes are both required to handle the scaled dimensions at the 5nm and 3nm nodes, and also the 3D nature of the scaled technologies – and here we are talking about logic and memories,” Verkest says. “With respect to depositions, we would need to develop thermal ALD processes (not plasma-based) that enable accurate and conformal depositions in non-line-of-sight structures.” Adhesion and wetting, smoothness, and throughput would also need to be addressed. “Longer term, these processes need to facilitate selectivity and self-alignment to address gap-fill challenges in highly scaled structures,” he says. Other concerns he notes with respect to atomic layer etches are selectivity to various materials, and fidelity requirements that increase the requirements for metrology accuracy. “Throughput is also a concern.”Bu believes that a new device architecture beyond FinFET is required to provide a full technology node scaling benefit (i.e., density, power and performance) at 5nm and 3nm. “Beyond 3nm, we may need to continue the transistor scaling in the vertical direction and start to stack them together,” Bu says. He also cites the need for parasitic R/C reduction in the interconnect to take advantage of the intrinsic transistor benefit at the circuit and chip levels. “We see a lot of opportunity in atomic-level processes, especially in atomic layer etch and selective material deposition, to address these challenges in the transistor and the interconnect.” Debra Vogler, SEMI
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